Document Type
Article
Publication Date
Summer 7-7-2007
Abstract
Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3).
Recommended Citation
MacMillan SN, Tanski JM, Waterman R. Insertion of benzyl isocyanide into a Zr-P bond and rearrangement. Atom-economical synthesis of a phosphaalkene. Chem Commun (Camb). 2007 Oct 28;(40):4172-4. doi: 10.1039/b709506f. http://pubs.rsc.org/en/content/articlepdf/2007/cc/b709506f
DOI
10.1039/b709506f