Document Type
Article
Publication Date
Summer 7-7-2007
Abstract
Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3).
Recommended Citation
MacMillan, S. N.; Tanski, J. M.; Waterman, R. Chem. Commun. 2007, 4172-4174. http://pubs.rsc.org/en/content/articlepdf/2007/cc/b709506f