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Insertion of Benzylisocyanide into a Zr-P bond and Rearrangement. Atom-Economical Synthesis of a Phosphaalkene

MacMillian, Samantha N
; 
Tanski, Joseph M
; 
Waterman, Rory
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10.1039/b709506f
Abstract
Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3).
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2007-07-07
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College of Arts and Sciences Faculty Publications
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Zr_rearrangement.pdf
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MacMillan SN, Tanski JM, Waterman R. Insertion of benzyl isocyanide into a Zr-P bond and rearrangement. Atom-economical synthesis of a phosphaalkene. Chem Commun (Camb). 2007 Oct 28;(40):4172-4. doi: 10.1039/b709506f. http://pubs.rsc.org/en/content/articlepdf/2007/cc/b709506f
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https://hdl.handle.net/20.500.14849/347
DOI
10.1039/b709506f
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