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Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine

Bange, Christine A.
; 
Mucha, Neil T.
; 
Cousins, Morgan E.
; 
Gehsmann, Abigail C.
; 
Singer, Anna
; 
Truax, Taylor
; 
Higham, Lee J.
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© 2016 by the authors.
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http://creativecommons.org/licenses/by/4.0/
Abstract
Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl- 4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosphine produces products with a complete selectivity for the secondary product. A key intermediate in catalysis, a zirconium phosphido compound, was isolated.
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2016-09-01
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Bange CA, Mucha NT, Cousins ME, Gehsmann AC, Singer A, Truax T, Higham LJ, Waterman R. Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine. Inorganics. 2016 Sep;4(3):26.
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https://hdl.handle.net/20.500.14849/345
DOI
10.3390/inorganics4030026
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