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Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine
Bange, Christine A. Mucha, Neil T. Cousins, Morgan E. Gehsmann, Abigail C. Singer, Anna Truax, Taylor Higham, Lee J.
Bange, Christine A.
Mucha, Neil T.
Cousins, Morgan E.
Gehsmann, Abigail C.
Singer, Anna
Truax, Taylor
Higham, Lee J.
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© 2016 by the authors.
DOI
10.3390/inorganics4030026
Abstract
Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl- 4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosphine produces products with a complete selectivity for the secondary product. A key intermediate in catalysis, a zirconium phosphido compound, was isolated.
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2016-09-01
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Waterman2016.pdf
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Bange CA, Mucha NT, Cousins ME, Gehsmann AC, Singer A, Truax T, Higham LJ, Waterman R. Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine. Inorganics. 2016 Sep;4(3):26.