Document Type
Article
Publication Date
9-1-2016
Abstract
Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl- 4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosphine produces products with a complete selectivity for the secondary product. A key intermediate in catalysis, a zirconium phosphido compound, was isolated.
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Rights Information
© 2016 by the authors.
Recommended Citation
Bange CA, Mucha NT, Cousins ME, Gehsmann AC, Singer A, Truax T, Higham LJ, Waterman R. Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine. Inorganics. 2016 Sep;4(3):26.
DOI
10.3390/inorganics4030026