Investigations Into Copper-Mediated Photocatalytic Hydroarsination

Presenter's Name(s)

Claire Bushey

Conference Year

2023

Abstract

Hydroarsination is an understudied reaction that can be utilized to synthetically produce products used in agriculture, medicine, and other fields. The reactivity of copper(II) acetylacetonate, Cu(acac)2, towards photocatalytic hydroarsination is explored through reactions with various substrates and product conversion monitored by NMR. Generation of a substrate scope for copper-mediated photocatalytic hydroarsination will allow for a deeper understanding that would allow for the development of more efficient systems. The chemical transformations studied will lead to the development of useful arsenic-containing products in an energy-efficient manner while simultaneously reducing chemical waste.

Primary Faculty Mentor Name

Rory Waterman

Status

Undergraduate

Student College

College of Arts and Sciences

Second Student College

Patrick Leahy Honors College

Program/Major

Chemistry

Primary Research Category

Physical Science

Abstract only.

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Investigations Into Copper-Mediated Photocatalytic Hydroarsination

Hydroarsination is an understudied reaction that can be utilized to synthetically produce products used in agriculture, medicine, and other fields. The reactivity of copper(II) acetylacetonate, Cu(acac)2, towards photocatalytic hydroarsination is explored through reactions with various substrates and product conversion monitored by NMR. Generation of a substrate scope for copper-mediated photocatalytic hydroarsination will allow for a deeper understanding that would allow for the development of more efficient systems. The chemical transformations studied will lead to the development of useful arsenic-containing products in an energy-efficient manner while simultaneously reducing chemical waste.